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High molecular weight copoly(ether ketone)s (PEK) based on 4-(4-hydroxyphenyl)- l-phthalazinone (DHPZ)/4,4'-thiobisphenol (TBP)/4,4'-diflourodiphenylketone (DFK) were prepared by nuclcophilic substitution polycondcnsation. The copolymers were char