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近处来,有关环状四核钼硫化合物的报道很多,这些同核钼硫化合物都是通过改变反应溶液的酸碱度和变换不同的有机配体或无机配体产生的,与之有关的固体合成尚未见文献报道.我们在探索低加热温度(100℃左右)下的配位化合物的固相反应过程中,已合成出了几十种新的同核或异核的Mo(W)-S化合物(包括含20种金属原子的大核簇合物[(n-Bu)_4N]_4[Mo_8Cu_(12)S_(32)]~[9]).标题化合物也是其中之一.本文将报道它的固相合成及晶体结构.
Recently, there have been many reports about cyclic tetranuclear molybdenum sulfur compounds, all of which are produced by changing the pH of the reaction solution and converting different organic ligands or inorganic ligands, and the related solid synthesis It has not been reported in the literature.We have synthesized dozens of new mononuclear or heteronuclear Mo (W) -S compounds in the course of exploring the solid phase reaction of coordination compounds at low heating temperatures (around 100 ° C) (Including large nuclear cluster containing 20 kinds of metal atoms [(n-Bu) _4N] _4 [Mo_8Cu_ (12) S_ (32)] to [9]) .The title compound is one of them. Solid Phase Synthesis and Crystal Structure.