论文部分内容阅读
着重介绍了用Bridgman方法生长的(1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3(PMN-PT)固溶体单晶在介电、压电、热释电性能及相变方面的一些特点:①异常高的压电常数d33(高达3000pC/N以上),耦合系数kt(在0.6以上),k33(达0.90),高的介电常数(高达5000甚至更高),低的Qm值(约60),热释电系数也较高.②强烈的各向异性.③随着PT含量的增加,系统的弛豫行为逐渐减弱,在x~0.33时,材料在室温下成为正常铁电体,但PE-FE相变并非正常铁电相变,表现为在T>Tm时; ~T关系不遵守居里-外斯定律,而是遵守Smolenskii的关系.该相变也明显地与弥散相变不同.这种行为可用无规场的观点加以解释. 对PMN-PT陶瓷,其压电性能与最好的软性PZT相似,而 和k31略大.
The characteristics of dielectric, piezoelectric, pyroelectric properties and phase transformation of (1-x) Pb (Mg1 / 3Nb2 / 3) O3-xPbTiO3 (PMN-PT) solid solution grown by Bridgman method are emphatically introduced : Abnormally high piezoelectric constant d33 (up to 3000 pC / N or more), coupling coefficient kt (above 0.6), k33 (up to 0.90), high dielectric constant (up to 5000 or higher), low Qm value (about 60), pyroelectric coefficient is also higher. ② strong anisotropy. (3) With the increase of PT content, the relaxation behavior of the system gradually decreases. At x ~ 0.33, the material becomes normal ferroelectric at room temperature, but the PE-FE phase transition is not normal ferroelectric phase transformation, T> Tm; the relationship of ~ T does not obey Curie-Weiss’s law, but obeys Smolenskii’s relation. This phase change is also clearly different from the dispersion phase change. This kind of behavior can be explained in terms of irregularities. For PMN-PT ceramics, the piezoelectric properties are similar to those of the best soft PZT, slightly larger than k31.