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用1,2-二(邻氨基苯氧基)乙烷分别与AgClO4和AgBF4进行配位反应,得到了两个配合物1,2,并用元素分析,FT-IR和X-射线单晶衍射进行了表征。结果表明,配合物1属于单斜晶系,C2/c空间群,配合物2属于单斜晶系,P21/c空间群。配合物1和2的每个Ag(Ⅰ)离子的配位环境均为扭曲的平面三角型,每个Ag(Ⅰ)离子与同一配体两端的氮原子配位,形成11元环状结构;然后,配体苯环上的碳原子与Ag(Ⅰ)离子配位,从而形成穴状双核配合物。
Coordination reaction with AgClO4 and AgBF4 with 1,2-bis (o-aminophenoxy) ethane gave two complexes 1, 2 and was characterized by elemental analysis, FT-IR and X-ray single crystal diffraction Characterization. The results showed that the complex 1 belongs to the monoclinic space group C2 / c and the complex 2 belongs to the monoclinic space group P21 / c. The coordination environment of each Ag (Ⅰ) ion in complexes 1 and 2 is a twisted planar trigonometry. Each Ag (Ⅰ) ion coordinates with the nitrogen atoms at the two ends of the same ligand to form a 11 - membered cyclic structure. Then, the carbon atom of the benzene ring of the ligand is coordinated with the Ag (I) ion to form a pocketed dinuclear complex.