pH-Dependent Assembly of Molecular Capsule,2D and 3D Coordination Polymers

• 作 者: LIN Rong-Guang
• 机 构: DepartmentofBiologyandChemistryEngineering,StateKeyLaboratoryofStructuralChemistry
• 出 处: 结构化学
• 发表日期: 2011年10期
• 关键词: 三维配位聚合物 分子胶囊 pH值 二维 依赖型 H2O 空间群 单斜晶系 4-sulfocalix[4]arene pH-dependent crystal s
• 基金项目: supported by the Natural Science Foundation of Fujian Province （2009J01018）, the Provincial Education Department of Fujian Project （JB08252）

Three lanthanum/4-sulfocalix[4]arene complexes,namely,H2[(H4CAS)La(H2O)7]2· H2[(H4CAS)La(H2O)7]2·2C2H5OH·12H2O(1),[H(H4CAS)La(H2O)5]·5H2O(2)and [(H4CAS)La-(H2O)4(NO3)La(H2O)5]·7H2O(3),have been synthesized at different pH conditio