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离子选择性电极研究络合物的络合平衡,具有筒单、准确等优点,并且能测定应用其它方法无法测定的体系。N.Bjerrum提出了一种图解求解各级稳定常数的方法,并且被得到了改进,但是都没有考虑同时存在金属离子和配位体离子副反应的情况。本文克服了这一不足,导出了测定各级稳定常数的统一处理实验数据的基本公式,此公式在形式上修正了前人的工作,并使其更加一般化,避免了较繁琐的计算工作,有
Ion-selective electrode complex complex research complex, with a single, accurate, etc., and can determine the use of other methods can not be determined system. N.Bjerrum proposed a method to graphically calculate the stability constants at various levels, and has been improved, but did not consider the simultaneous presence of metal ions and ligand ion side reactions. This paper overcomes this problem and derives the basic formula for the unified processing of experimental data for the determination of the stability constants at all levels. This formula formally amends the predecessors’ work and makes it more generalized, avoiding the more complicated calculation work. Have