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The title complex nBuSn(O)(tsglyO)6·6CHCl3 (tsglyO=N-p-tolysulfonyl-glycinate monoanion) was syn- thesized by the reaction of nBuSn(O)OH with N-p-tolysulfonyl-glycine in 1∶1 molar ratio. The complex was charac- terized by IR, 1H NMR spectra and elemental analysis. The crystal structure was determined by X-ray diffraction method. It crystallizes in rhombohedral system with space group R3. The crystal data are: a=b=2.7387(4) nm, c= 1.4465(4) nm, α=β=90°, γ=120°, Z=6, Dc=1.726 g·cm-3, F(000)=4878, V=9.396(3) nm3, R1=0.0325, wR2=0.089 8. The structure shows a distorted octahedral configuration with six-coordination for the central tin atom. CCDC: 274183.
The title complex nBuSn (O) (tsglyO) 6.6CHCl3 (tsglyO = Np-tolysulfonyl-glycinate monoanion) was syn- thesized by the reaction of nBuSn (O) OH with Np-tolysulfonyl- glycine in a 1: 1 molar ratio. The complex was chacu- terized by IR, 1H NMR spectra and elemental analysis. The crystal structure was determined by X-ray diffraction method. The crystal structure was determined by X-ray diffraction method. α = β = 90 °, γ = 120 °, Z = 6, Dc = 1.726 g · cm -3, F (000) = 4878, V = 9.396 (3) nm 3, R1 = 0.0325, wR2 = 0.089 8. The structure shows a distorted octahedral configuration with six-coordination for the central tin atom. CCDC: 274183.