High Rate and Long Lifespan Sodium?Organic Batteries Using Pseudocapacitive Porphyrin Complexes?Base

• 作 者: Xi Chen Xin Feng Bo Ren Liangzhu Jiang Hongbo Shu Xiukang Yang Zhi Chen Xiujuan Sun Enhui Liu Ping Gao
• 机 构: Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Key L
• 出 处: 纳微快报（英文）
• 发表日期: 2021年5期
• 关键词: Organic cathode Sodium-organic batteries Porphyrin complex Rechargeable batterie

Sodium-organic batteries utilizing natural abundance of sodium element and renewable active materials gain great attentions for grid-scale applications. However, the development is still limited by lack of suitable organic cathode materials with high electronic conductivity that can be operated stably in liquid electrolyte. Herein, we present 5,15-bis(ethynyl)-10,20-diphenylporphyrin (DEPP) and [5,15-bis(ethynyl)-10,20-diphenylporphinato]copper(II) (CuDEPP) as new cathodes for extremely stable sodium-organic batteries. The copper(II) ion partially contributes the charge storage and significantly stabilizes the structure of porphyrin complex for electrochemical energy storage. In situ electrochemical stabilization of organic cathode with a lower charging current density was identified which enables both improved high energy density and power density. An excellent long-term cycling stability up to 600 cycles and an extremely high power density of 28 kW kg?1 were achieved for porphyrin-based cathode. This observation would open new pathway for developing highly stable sodium-organic cathode for electrochemical energy storage.