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  5. CuCl/Zn-promoted Mukaiyama Aldol Reaction of Phenyl a-fluoro silyl enol ether with Aldehydes

CuCl/Zn-promoted Mukaiyama Aldol Reaction of Phenyl a-fluoro silyl enol ether with Aldehydes

来源 :Chinese Journal of Chemistry | 被引量 : 0次 | 上传用户：guchenbing
【摘 要】
：
Fluoro-1-phenyl-1-trimethylsiloxyethene reacted efficiently with aldehydes to give a-fluoro -hydroxy ke-tones in HMPA in the presence of Zn powder and CuCl. Fl
【作 者】
：
周鼎英 陈庆云 
【机 构】
：
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry,Chinese Academy
【出 处】
：
Chinese Journal of Chemistry
【发表日期】
：
2004年09期
【关键词】
：
fluoro CuCl promoted aldehydes carbonyl Phenyl aromatic selectivity unsaturated 
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Fluoro-1-phenyl-1-trimethylsiloxyethene reacted efficiently with aldehydes to give a-fluoro -hydroxy ke-tones in HMPA in the presence of Zn powder and CuCl. Fluoro-1-phenyl-1-trimethylsiloxyetrate efficiently with aldehydes to give a-fluoro -hydroxy ke-tones in HMPA in the presence of Zn powder and CuCl.
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