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η5-Pentamethylcyclopentadienyl-(η5-exo-tricyclo[5.2.1.02,6]deca-2,5,8-trien-6-yl) iron(3) was synthesized and characterized by 1H NMR, 13C NMR, MS, elemental analysis, IR, UV and X-ray diffraction analysis. Compound 3 was polymerized with ring-opening metathesis polymerization(ROMP) initiator (PCy3)2Cl2Ru=CHPh. 1H NMR and IR spectra revealed the presence of CH=CH units in the polymer and supported the ROMP mechanism. GPC analysis of the polymer showed that the weight-average molecular weights(Mw) was 5967, and the polydispersity index(PDI) was 1.16. The polymer was also investigated by UV and cyclic voltammetry.
η5-Pentamethylcyclopentadienyl- (η5-exo-tricyclo [5.2.1.02,6] deca-2,5,8-trien-6-yl) iron (3) synthesized and 1H NMR, 13C NMR, MS, elemental analysis Compound 3 was polymerized with ring-opening metathesis polymerization (ROMP) initiator (PCy3) 2Cl2Ru = CHPh. 1H NMR and IR spectra showed the presence of CH = CH units in the polymer and supported the ROMP mechanism. GPC analysis of the polymer showed that the weight-average molecular weights (Mw) was 5967, and the polydispersity index (PDI) was 1.16. The polymer was also investigated by UV and cyclic voltammetry.