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利用光谱电化学方法来研究冠醚类化合物的文章尚未见报导.本文在测定用凝胶法合成的[Co(H_2O)(NCS)_2](18-C-6)的核磁共振谱和红外光谱的基础上,使用循环伏安法和薄层光谱电化学技术,在金微栅电极上测定了此配合物在乙腈溶剂中的第一步克式量电势(E~0′)和电子转移数(n),并推测了电还原反应机理.
There are no reports about the use of the spectrochemical method to study the crown ethers. In this paper, the determination of [Co (H_2O) (NCS) 2] (18-C-6) , The cyclic voltammetry and TLCS were used to measure the first step potential (E ~ 0 ’) and electron transfer number of this complex in acetonitrile solvent on gold micro grid electrode (n), and speculated that the mechanism of electro-reduction reaction.