Propylene Polymerization Catalysts with Sulfonyl Amines as Internal Electron Donors

• 作 者: Wang Liang Yin Baozuo Yi Jianj
• 机 构: StateKeyLaboratoryofElemento-OrganicChemistry,PetrochemicalResearchInstitute
• 出 处: 中国炼油与石油化工：英文版
• 发表日期: 2013年2期
• 关键词: 聚合催化剂 内给电子体 聚丙烯 ZIEGLER-NATTA 磺酰胺类 可见分光光度法 电子给体 催化剂性能 heterogeneous catalyst po
• 基金项目: the PetroChina for the financial support(Contract Number:08-07-01-20)

Three sulfonyl aliphatic amines [(R2SO2)2NR1 , viz.: compound 1, in which R1 =Me, and R2 =Ph; compound 2, in which R1=n-Bu, and R2 =CF3 ; and compound 3, in which R1 =C8H17 , and R2 =CF3], have been synthesized and employed as internal electron donors (IE