Electroless copper-phosphorus coatings with the addition of silicon carbide (SiC) particles

来源 :International Journal of Minerals Metallurgy and Materials | 被引量 : 0次 | 上传用户:liongliong590
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Cu-P-silicon carbide (SiC) composite coatings were deposited by means of electroless plating.The effects of pH values,temperature,and different concentrations of sodium hypophosphite (NaH2PO2·H2O),nickel sulfate (NiSO4·6H2O),sodium citrate (C6H5Na3O7·2H2O) and SiC on the deposition rate and coating compositions were evaluated,and the bath formulation for Cu-P-SiC composite coatings was optimised.The coating compositions were determined using energy-dispersive X-ray analysis (EDX).The corresponding optimal operating parameters for depositing Cu-P-SiC are as follows:pH 9;temperature,90oC;NaH2PO2·H2O concentration,125 g/L;NiSO4·6H2O concentration,3.125 g/L;SiC concentration,5 g/L;and C6H5Na3O7·2H2O concentration,50 g/L.The surface morphology of the coatings analysed by scanning electron microscopy (SEM) shows that Cu particles are uniformly distributed.The hardness and wear resistance of Cu-P composite coatings are improved with the addition of SiC particles and increase with the increase of SiC content. Cu-P-silicon carbide (SiC) composite coatings were deposited by means of electroless plating. The effects of pH values, temperature, and different concentrations of sodium hypophosphite (NaH2PO2 · H2O), nickel sulfate C6H5Na3O7.2H2O) and SiC on the deposition rate and coating compositions were evaluated, and the bath formulation for Cu-P-SiC composite coatings was optimized. The coating compositions were determined using energy-dispersive X-ray analysis (EDX). The optimal operating parameters for depositing Cu-P-SiC are as follows: pH 9; temperature, 90oC; NaH2PO2 · H2O concentration, 125 g / L; NiSO4 · 6H2O concentration, 3.125 g / C6H5Na3O7 · 2H2O concentration, 50 g / L. The surface morphology of the coatings analyzed by scanning electron microscopy (SEM) shows that Cu particles are uniformly distributed. Hardness and wear resistance of Cu-P composite coatings are improved with the addition of SiC particles and increase with the in crease of SiC content.
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