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In the title compound, [Pb2(C8H4O4)2(C19H12N4O)2]n·3.5nH2O (1), has been synthesized by the hydrothermal assembly of 1,4-benzenedicarboxylate and 4-(1H-1,3,7,8-tetraazacyclopenta[l]-phenanthren-2-yl)phenol(TCPP) with lead acetate. Elemental analysis, X-ray crystal structure analysis, IR spectrum, thermogravimetric analysis and luminescence property were carried out for the structural determination and characterization of the title compound. Compound 1 crystallizes in triclinic, space group P1 with a=1.013 54(10) nm, b=1.104 84(11) nm, c=1.210 05(12) nm, α=76.812 0(10)°, β=74.814 0(10)°, γ=86.030 0(10)°, V=1.273 1(2) nm3, Pb2C54H39N8O13.5, Mr=1 430.31, Z=1, Dc= 1.866 g·cm-3, μ=6.680 mm-1, F(000)=691, R=0.027 3 and wR=0.068 7 for 4 042 observed reflections (I>2σ(I)). The compound 1 exhibits two-dimensional network structures, which are further stacked through π-π interactions and hydrogen bonds to form three-dimensional supramolecular polymer. Solid-state luminescent spectrum of the compound 1 indicates intense fluorescent emission. CCDC: 748883.
In the title compound, [Pb2 (C8H4O4) 2 (C19H12N4O) 2] n.3.5nH2O (1), has been synthesized by the hydrothermal assembly of 1,4-benzenedicarboxylate and 4- (1H- phenanthren-2-yl) phenol (TCPP) with lead acetate. Elemental analysis, X-ray crystal structure analysis, IR spectrum, thermogravimetric analysis and luminescence property were carried out for the structural determination and characterization of the title compound 1 crystallizes in triclinic, space group P1 with a = 1.013 54 (10) nm, b = 1.104 84 (11) nm, c = 1.210 05 (12) nm, 74.814 0 (10) °, γ = 86.030 0 (10) °, V = 1.273 1 (2) nm3, Pb2C54H39N8O13.5, Mr = 1 430.31, Z = 1, Dc = 1.866 g · cm -3, μ = 6.680 mm -1, F (000) = 691, R = 0.027 3 and wR = 0.068 7 for 4 042 observed reflections (I> 2σ (I)). The compound 1 exhibits two-dimensional network structures which are further stacked through π -π interactions and hydrogen bonds to form three-dimensional supramolecular polymer. Solid-state luminescent spectrum of the compound 1 indicates intense fluorescent emission. CCDC: 748883.