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The crystal structure of the title compound [Mn(sapn)(H2O)2]Br (H2sapn = N,N?bis-(salicylidene)-1,3-diaminopropane) with formula C17H18N2O4MnBr and Mr = 449.18 has been determined by X-ray diffraction. The crystal is triclinic with space group P , a = 7.777(1), b = 10.459(2), c = 11.96(3), = 78.22(1), =75.16(8), = 86.80(5)? V = 919(3)3, Dc = 1.631g/cm3, F(000) = 456, = 2.917 cm-1 and Z = 2, with R = 0.0428 and wR = 0.1092 for 2427 reflections (I > 2s(I)). Two nitrogen and two oxygen atoms from the sapn group chelate to the MnⅢ ion, forming a distorted octahedral geometry together with two coordinated water molecules. A bromide anion exists outside as a counter ion.
The crystal structure of the title compound [Mn (sapn) (H2O) 2] Br (H2sapn = N, N? Bis- (salicylidene) -1,3- diaminopropane) with formula C17H18N2O4MnBr and Mr = 449.18 has been determined by X- ray diffraction. The crystal is triclinic with space group P, a = 7.777 (1), b = 10.459 (2), c = 11.96 (3), = 78.22 (1), = 75.16 (8), = 86.80 V = 919 (3) 3, Dc = 1.631 g / cm3, F (000) = 456, = 2.917 cm- 1 and Z = 2 with R = 0.0428 and wR = 0.1092 for 2427 reflections )). Two nitrogen and two oxygen atoms from the sapn group chelate to the Mn III ion, forming a distorted octahedral geometry together with two coordinated water molecules. A bromide anion exists outside as a counter ion.