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We have studied TV content influence in two ranges of x(R1.,R2) by Raman, PL, IR spectra on PCVD a-Si:H/a-SiNx:H samples with constant sublayer thickness and cycle number but whole range of x respectively. Raman shows that the FWHM of TO-like peaks increases with x in range R1 and so does the bond angle fluctuation. PL exhibits that the band tail width increases and the NR activation energy as well as the PL efficiency decrease? with x in R1, because of the increase of lattice strain introduced by structural mismatch at interfaces. The above parameters change towards the opposite direction in R2 with a turn at x=0.9, This might be caused by the structure change of a-SiNx into Si3N4 and the greatly increasing of N-H bonds in R2, which enhances the softness of the matrix and relaxes the lattice strain.
We have studied TV content influence in two ranges of x (R1., R2) by Raman, PL, IR spectra on PCVD a-Si: H / a-SiNx: H samples with constant sublayer thickness and cycle number but whole range of x respectively. Raman shows that the FWHM of TO-like peaks increases with x in range R1 and so does the bond angle fluctuation. PL exhibits that the band tail width increases and the NR activation energy as well as the PL efficiency decrease? with x in R1, because of the increase of lattice strain introduced by structural mismatch at interfaces. The above parameters change towards the opposite direction in R2 with a turn at x = 0.9, This might be caused by the structure change of a-SiNx into Si3N4 and the greatly increasing of NH bonds in R2, which enhances the softness of the matrix and relaxes the lattice strain.