论文部分内容阅读
以有机磷酸酯为掺杂剂、过硫酸铵为引发剂,采用化学氧化法合成导电聚苯胺。在苯胺浓度为0.1mol/L、有机磷酸酯浓度为0.3mol/L、过硫酸铵浓度为0.12mol/L、温度10℃、聚合反应时间3.5小时的条件下,合成了电导率达0.42s/cm的聚苯胺。采用红外光谱和X-射线衍射对其结构进行了表征。
Using organic phosphate as dopant and ammonium persulfate as initiator, the conductive polyaniline was synthesized by chemical oxidation. Under the conditions of aniline concentration of 0.1 mol / L, organic phosphate concentration of 0.3 mol / L, ammonium persulfate concentration of 0.12 mol / L, temperature of 10 ° C and polymerization time of 3.5 hours, conductance Polyaniline with a rate of 0.42 s / cm. Its structure was characterized by infrared spectroscopy and X-ray diffraction.