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硼化钛是近年来很受重视的特种陶瓷材料,其特点是耐高温、抗腐蚀、导电性好,因而被认为是一种在结构材料和功能材料领域中都很有发展前途的材料。该论文通过对KClNaClK2TiF6KBF4体系中Ti(Ⅳ)、B(Ⅲ)的阴极电极过程及电化学合成TiB2的研究,探讨了该体系中Ti(Ⅳ)、B(Ⅲ)的阴极放电机理,确定了熔盐电解法制备TiB2的优化操作条件。
Titanium boride is a special ceramic material that has gained much attention in recent years. It is characterized by its high temperature resistance, corrosion resistance and good electrical conductivity. Therefore, it is considered as a promising material for both structural and functional materials. In this paper, the cathode electrode process of Ti (Ⅳ) and B (Ⅲ) in KClNaClK2TiF6KBF4 system and the electrochemical synthesis of TiB2 were studied. The cathodes of Ti (Ⅳ) and B (Ⅲ) Discharge mechanism to determine the optimal operating conditions for the preparation of TiB2 by molten salt electrolysis.