THE CRYSTAL AND MOLECULAR STRUCTURE OF N,N~'-DI-n-BUTYL-29,30-DIMBTHOXY-13,27-DICHLORO-6,20-DIA

• 出 处: 结构化学
• 发表日期: 1987年01期
• 关键词: triclinic shaped approximate refinement separate hexane inversion 书书书 七户 Phenyl

C34H52N2O6Cl2, Mr=655.70, triclinic, Pl,a=8.909(5),b=9.158(5), c=11.841(9) A,α=73.41(5)°,β=76.51(8)°,γ=80.38(6)°, V = 895.1 A3, Z=l, DC=1.223 gcm-3,λ= 0.7107 A,μ=2.299 cm-1.Full matrix least-squares refinement, final R = 0.088, Rw= 0.084 for 1039 (I>36) unique reflections. The crystal is composed of separate molecules having an approximate inversion center. The molecule is shaped like an ellipse. The distances of 0(31)-0(32), 0(41)-0(42), and N(31)-N(41) are 4.254, 4.136 and 10.930 A, respectively.

Α = 73.41 (5) °, β = 76.51 (8) °, γ = 0.763, 80.38 (6) °, V = 895.1 A3, Z = 1, DC = 1.223 gcm-3, λ = 0.7107 A, μ = 2.299 cm- 1.Full matrix least-squares refinement, final R = 0.088, Rw = 0.084 for 1039 (I> 36) unique reflections. The crystal is composed of separate molecules having an approximate inversion center. The distances of 0 (31) -0 (32), 0 (41) -0 42), and N (31) -N (41) are 4.254, 4.136 and 10.930 A, respectively.