Energy transfer of n-hexane-tributyl phosphate(TBP)binary system:Using TBP as a probe for the detect

• 出 处: Acta Chimica Sinica(English Edition)
• 发表日期: 1985年01期
• 关键词: hexane excited ketone irradiation detecting benzene labeled sensitized transferr

In this paper TBP labeled with ~(32)p was used as a probe for detecting the excited speciesof n-hexane.Under γ irradiation of n-hexane-TBP binary system,it was found that TBP was sen-sitized by excited n-hexane molecules and a G value of 1.05 was found for the excited state of n-hexane.An energy transfer mechanism was proposed,and kinetic equation of sensitization was obtained.Theoretical calculation is in agreement with experimental results.

In this paper TBP labeled with ~ (32) p was used as a probe for detecting the excited species of n-hexane.Under γ irradiation of n-hexane-TBP binary system, it was found that TBP was sen-sitized by excited n- hexane molecules and a G value of 1.05 was found for the excited state of n-hexane. An energy transfer mechanism was proposed, and kinetic equation of sensitization was obtained.