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The preparation of X-zeolite powder was investigatedin hydrothermal system, the crystal growth process of X-zeolite in hydrothermal condition was characterized by means of X-ray diffraction, scanning electron microscope and infrared ray. The results show that X-zeolite powder with uniform granularity and intact crystal shape can be obtained in hydrothermal system of acid-treated stellerite-NaOH-NaAl(OH)4-H2O; the crystallite size is in the range of 2 - 3μm. The best reaction time of hydrothermal preparation is 6 h. The formation phases of X-zeolite crystal are as follows: dissolution of feedstocks → formation of [SiO4]4- and [AlO4]5- tetrahedron, many-membered ring,β cage → formation of crystal nucleus and nano-particle → aggregation growth of nano-particle → coalescence growth of crystallite. The crystal habits of X-zeolite are intimately related with crystallization orientation ofβ cage in crystal and with its coupling stability on every crystal face family.