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合成了两个镉金属配合物,[Cd2(NDA)2(phen)2](H2O)(1)和[Cd(phen)2(NO3)2](2),其中,NDA为外降冰片烯-顺-5,6二羧酸.其固体状态结构通过红外和单晶衍射进行了表征.第一个化合物属于三斜晶系,P-1空间群.a=9.444 3(12),b=10.800 4(14),c=10.979(2)A,α=104.034(3),β=95.618(3),γ=111.785(2)o,V=986.7(3)A3,Z=1,Dc=1.692g/cm3,F(000)=508和μ=1.146mm-1(λ=0.710 73A),R=0.071 1,wR=0.201 6f.该化合物分子是通过羧基的氧原子采用的双齿桥配位模式.其中,Cd…Cd分子间距离为4.901A.第一个化合物为的七配位构型,而第二个为八配位构型.该化合物热重分析显示该化合物在260℃下是稳定的.
Two cadmium metal complexes, [Cd2 (NDA) 2 (phen) 2] (H2O) (1) and [Cd (phen) 2 (NO3) 2] - cis-5,6 dicarboxylic acid. The solid state structure was characterized by IR and single crystal diffraction. The first compound belongs to the triclinic system, P-1 space group. A = 9.444 3 (12), b = A = 104.034 (3), β = 95.618 (3), γ = 111.785 (2) o, V = 986.7 (3) A3, Z = 1, ΛDc = 1.692g / cm3, F (000) = 508 and μ = 1.146mm-1 (λ = 0.71073A), R = 0.071 1, wR = 0.201 6f. This compound molecule is a bis Bridged coordination mode, in which, the Cd ... Cd intermolecular distance is 4.901A. The first compound is a seven-coordinate configuration and the second one is an octa-coordinated configuration. The thermogravimetric analysis of the compound Stable at 260 ° C.