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利用常规方法合成了一个Anderson型多酸化合物[(H2bbi)(CrMo6H7O24)]·4H2O,并通过元素分析和X-射线单晶衍射仪对其进行结构表征。该化合物属于三斜晶系,P-1空间群,a=7.8223(7),b=8.9003(9),c=12.1326(10),α=86.193(7)°,β=86.951(7)°,γ=76.752(8)°,V=819.76(13)3,Z=1。多酸阴离子、bbi配体和游离的水分子之间通过氢键作用形成三维超分子网状结构。
Anderson-type polyacid compound [(H2bbi) (CrMo6H7O24)] · 4H2O was synthesized by conventional methods and its structure was characterized by elemental analysis and X-ray single crystal diffraction. The compound belongs to the triclinic system with a = 7.8223 (7) , b = 8.9003 (9) , c = 12.1326 10, α = 86.193 (7) °, β = 86.951 7) °, γ = 76.752 (8) °, V = 819.76 (13) 3, Z = 1. Polyacid anion, bbi ligand and free water molecules formed by hydrogen bonding three-dimensional supramolecular network structure.