【摘 要】
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High order centrifugal distortion terms have been derived and added to the effective Hamiltonian of asymmetric top molecules. Based on this Hamiltonian, a progr
【机 构】
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State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics,Wuhan Institute of Physi
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High order centrifugal distortion terms have been derived and added to the effective Hamiltonian of asymmetric top molecules. Based on this Hamiltonian, a program in Fortran 77 has been developed for spectral analysis of asymmetric top molecules. The high order centrifugal distortion terms are found to be non-negligible even for the low-lying rotational transitions of molecules, such as Ha 18O, subjected to severe centrifugal distortion effect,and for the high-lying rotational transitions of molecules, such as 14N16O2 subjected to the moderate centrifugal distortion effect.
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