XPS Study on Barium Lanthanum Magnesium Niobate

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:haizhiren
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Relaxor-type ferroelectric perovskites attract a lot of attentions due to their excellent dielectric and electrostrictive properties. (Ba,La)(Mg, Nb)O3(BLMN) ceramics were synthesized from oxides by sintering in airs using a conventional mixed oxide process. Thermogravimetry-differential analyzer (TG-DTA) analysis shows that the fired temperature of the Ba(Mg1/3, Nb2/3)O3 is above 1627.2 K. From the study of X-ray diffraction (XRD) patterns, it is founded that the amount of the perovskite phase increases with the increasing amount of La2O3. Furthermore, by the X-ray photoelectron spectroscopy (XPS) analysis, it is discovered that the amount of Nb4+ is increased as La2O3 dopant increases from 0 to 0.04. Relaxor-type ferroelectric perovskites attract a lot of attentions due to their excellent dielectric and electrostrictive properties. (Ba, La) (Mg, Nb) O3 (BLMN) ceramics were synthesized from oxides by sintering in airs using a conventional mixed oxide process. Thermogravimetry It is found that the diffraction angle of the Ba (Mg1 / 3, Nb2 / 3) O3 is above 1627.2 K. From the study of X-ray diffraction amount of the perovskite phase increases with the increasing amount of La2O3. By the X-ray photoelectron spectroscopy (XPS) analysis, it was discovered that the amount of Nb4 + is increased as La2O3 dopant increases from 0 to 0.04.
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