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The tetra(2, 4-dichlorobenzyl)tin was synthesized and characterized by elementary analysis, IR and 1H NMR. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal of the title compound belongs to triclinic, space group P1 with a=1.089 7(3) nm, b=1.050 33(4) nm, c=1.858 5(4) nm, α=96.822(4)°, β=94.477(4)°, γ=94.636(3)°, V=3.001 3(12) nm3, Z=4, Dc=1.679 Mg·m-3, μ(Mo Kα)=1.582 mm-1, S=1.005, F(000)=1 496, R1=0.040 7, wR2=0.076 3. In compound, the tin atom has a distorted tetrahedral coordination configuration. The molecules are packed in one-dimensional chain polymer through a weak interaction between the chlorine atoms from adjacent molecules, respectively. CCDC: 286106.
The tetra (2, 4-dichlorobenzyl) tin was synthesized and characterized by elementary analysis, IR and 1H NMR. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal of the title compound belongs to triclinic, space group (4) °, β = 94.477 (4) °, γ = 94.636 (3) where P1 = 1.089 7 (3) nm and b = 1.050 33 ) =, V = 3.001 3 (12) nm3, Z = 4, Dc = 1.679 Mg · m-3, μ (Mo Kα) = 1.582 mm-1, S = 1.005, F (000) = 1 496, 0.040 7, wR2 = 0.076 3. In compound, the tin atom has a distorted tetrahedral coordination configuration. The molecules are packed in one-dimensional chain polymer through a weak interaction between the chlorine atoms from adjacent molecules, respectively. CCDC: 286106.