【摘 要】
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Main observation and conclusionrnRing-opening metathesis polymerization (ROMP) is a powerful toolbox in preparation of bottlebrush polymers for its high activit
【机 构】
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School of Materials Science and Engineering,Tianjin Key Laboratory of Composite and Functional Mater
论文部分内容阅读
Main observation and conclusionrnRing-opening metathesis polymerization (ROMP) is a powerful toolbox in preparation of bottlebrush polymers for its high activity.However,the ROMP of macromonomers with repeating tertiary amine groups,for example,poly(2-(dimethylamino)ethyl methacry-late) (PDMAEMA),is inhibited due to the coordination of nitrogen atom with ruthenium center ([Ru]) in the third generation Grubbs catalyst (G3).In this work,norbornenyl functionalized polystyrene-block-PDMAEMA (NB-PS-b-PDMAEMA) macromonomers with dif-ferent length of polystyrene (PS) spacers are prepared.
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