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Chen P等[Tetrahedron Lett,2011,52:5758]消旋的烯丙醇在甲苯中,脂肪酶PS-30催化下,可与乙酸乙烯酯发生立体选择性酰化反应,从而实现其动力学拆分,得到相应的光学纯乙酸烯丙酯和另一构型的未反应的烯丙醇。11
Chen P et al [Tetrahedron Lett, 2011, 52: 5758] racemic allyl alcohol can be stereoselectively acylated with vinyl acetate catalyzed by lipase PS-30 in toluene to achieve its kinetic resolution Min to give the corresponding optically pure allyl acetate and another configuration of unreacted allyl alcohol. 11