Synthesis of furan from allenic sulfide derivatives

• 作 者: LingLing Peng (1) (2) Xiu Zh
• 机 构: 1.CollegeofChemistry,2.KeyLaboratoryofBioorganicChemistryandMolecularEngineeringofMinistryofEducatio
• 出 处: 中国科学：化学英文版
• 发表日期: 2009年10期
• 关键词: FURAN ALLENE SYNTHETIC method NUCLEOPHILIC reaction furan allene synthetic metho
• 基金项目: Supported by the National Natural Science Foundation of China (Grant Nos. 20832002, 20772003 & 20821062),973 Project (Grant No. 2009CB825300)

In this paper, we report the synthesis of furan derivatives from allenic sulfides. By the reaction with NaH, β-Hydroxyl allenic sulfides were found to generate furan products in excellent yields with the removal of phenylthio group. β-Aldehyde allenic sul