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TEACO_2激光(10.6μm)照射甲基氯化汞的酸性水溶液,可以断裂碳—汞键,功率密度越大或照射次数越多,碳—汞键断裂的百分数也越高。照射过程中,液相体系的温度变化缓慢,我们认为此反应是多光子吸收的解离反应。
The TEACO_2 laser (10.6μm) irradiation with methyl mercuric chloride aqueous solution can break the carbon-mercury bond. The higher the power density or the number of irradiation, the higher the percentage of carbon-mercury bond rupture. During the irradiation, the temperature of the liquid phase system changes slowly. We think this reaction is the dissociation reaction of multiphoton absorption.