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This study aims to understand the effects of functional agents such as capping agents, stabilizers, surfactants and additives in shape-controlled synthesis of nanomaterials. The well-defined Pt(100) single crystal surface was used as a model to investigate its interaction with citrate, a capping agent that is often used in shape-controlled synthesis of nanomaterials. It demonstrated that, through a systematic study of electrochemical cyclic voltammetry, the presence of citrate in solution could increase the current peak density of hydrogen adsorption at high potential (j p,L ), while decrease proportionally the current peak density of hydrogen adsorption at low potential (j p,S ). Furthermore, the increase of citrate concentration shifted negatively the peak potentials (E p,L and E p,S ) of both j p,L and j p,S . The results indicated that the interaction of citrate with Pt(100) surface could induce increasing the (100) surface domains of two-dimensional long range order (2D-(100)), and decreasing the (100) surface domains of one-dimensional short range order (1D-(100)). It also revealed that the interaction of citrate with Pt(100) surface could stabilize the 2D-(100) structure. The findings gained in this study implied that the citrate may lead to form stable 2D-(100) domains on Pt nanoparticles upon the shape-controlled synthesis of Pt nanomaterials.
This study aims to understand the effects of functional agents such as capping agents, stabilizers, surfactants and additives in shape-controlled synthesis of nanomaterials. The well-defined Pt (100) single crystal surface was used as a model to investigate its interaction with citrate , a capping agent that is often used in shape-controlled synthesis of nanomaterials. It demonstrated that, through a systematic study of electrochemical cyclic voltammetry, the presence of citrate in solution could increase the current peak density of hydrogen adsorption at high potential (jp, L), while decreasing proportionally the current peak density of hydrogen adsorption at low potential (jp, S). Furthermore, the increase of citrate concentration shifted negative peak of the peak potentials (E p, L and E p, S) of both jp, L and jp, S. The results indicated that the interaction of citrate with Pt (100) surface could induce increasing (100) surface domains of two-dimensional long range order (2D- (100)), an d decreasing the (100) surface domains of one-dimensional short range order (1D- (100)). It also revealed that the interaction of citrate with Pt (100) surface could stabilize the 2D- (100) structure. in this study implied that the citrate may lead to form stable 2D- (100) domains on Pt nanoparticles upon the shape-controlled synthesis of Pt nanomaterials.