【摘 要】
:
Today,nanocrystals enclosed by high-index facets (HIFs) are attracting widely attentions of researchers due to their tremendous potential in the field of catalysis,especially in electrocatalysis,such as electro-oxidation of small organic molecule (such as
【机 构】
:
State Key Laboratory of Heavy Oil Processing,College of Chemical Engineering and Environment,China U
论文部分内容阅读
Today,nanocrystals enclosed by high-index facets (HIFs) are attracting widely attentions of researchers due to their tremendous potential in the field of catalysis,especially in electrocatalysis,such as electro-oxidation of small organic molecule (such as formic acid,methanol,and ethanol),oxygen reduction reaction (ORR),hydrogen evolution reaction (HER),as well as the oxygen evolution reaction (OER).However,the practical applications of nanocrystals enclosed by HIFs still face many limitations in preparations of advanced electrocatalysts,including preparation strategy,limited life-time and stability.The development of advanced electrocatalysts enclosed with HIFs is crucial for solving these problems if the large-scale application of them is to be realized.Herein,we firstly detailedly demonstrate the identification methods of nanocrystals enclosed by HIFs,and then preparation strategies are elaborated in detail in this review.Current advanced nanocrystals enclosed by HIFs in electrocatalytic application are also summarized and we present represen-tative achievements to further reveal the relationship of excellent electrocatalytic performance and nanocrystals with HIFs.Finally,we predict the remaining challenges and present our perspectives with regards of design strategies of improving electrocatalytic performance of Pt-based catalysts in the future.
其他文献
计算机实验室是一种特殊的局域网,是重要的云端部分,能够实现Internet的各种基本功能.其不仅承担各种计算机课程的教学实验,学生自主学习、自由上机实践等任务,还作为各种无纸化考试的重要场所等,因此,计算机实验室的科学管理、自动化管理就显得尤为重要.本文从构建终端地址池、云部署服务平台,建立系统软件云、硬盘模板库几个方面进行阐述,以期为增强计算机实验室的管理提供参考.
Aluminum hydride (AlH3) is a covalently bon-ded trihydride with a high gravimetric (10.1 wt%) and volumetric (148 kg.m-3) hydrogen capacity.AlH3 decomposes to Al and H2 rapidly at relatively low tem-peratures,indicating good hydrogen desorption kinetics a
随着人工智能的快速发展,创客教育在全国悄然兴起,开源硬件作为创客教育的技术核心,发挥着重要的作用.小学着重培养学生综合能力和综合素质,是开源硬件课程开展实施的沃土.但从实际开展情况来看,开源硬件教学目前仍然停留在“技术本位”为主的阶段.技术只是工具,思维的培养才是核心.开源硬件不仅是指硬件制作与开放学习的课程,更强调的是创新思维与能力的培养,而技术本位的教学方式不能达成这一目标.要解决这一问题需要长期的探索与实践,教师需要在日常教学中转变观念,将思维培养放在核心地位逐步培养.思维可视化是将“只可意会不可言
作者利用信息技术等现代手段摹制、刻制我国宋刻本古籍,在制作、欣赏过程中体会国学知识,进而培养学生核心素养.虽然制作成本低廉,但是摹制的宋刻本古籍可以与专业出版社水平相媲美.
Hydrogen is considered to be an ideal safe and clean energy source,which can be produced by water splitting.The high overpotential of hydrogen evolution reaction (HER) is one of the bottleneck issues for the practical application of water splitting,where
本文以《Excel数据图表》一课为例,从四个方面阐述了以技术支持信息技术教学的实施过程,旨在技术助力教学方式的改变,提升教学效率.这四个方面分别是:采用微课助力教学重难点的解决;在线考试工具助力课堂教学效果检测;思维导图助力知识总结、归纳;云存储工具助力课堂延伸.
Two-dimensional (2D) transition metal dichalcogenides (TMDCs) have attracted growing interest regarding their potential applications in next-generation electronic and optoelectronic devices.Owing to their atomic thickness and tunable bandgap,they exhibit
Combining metal to form metal phosphide is a promising strategy to address the fast capacity decay of P rooted from its low electronic conductivity and large vol-ume changes upon cycling.Cu3P,which possesses a high theoretical gravimetric and volumetric c
Metallic nanoparticles (NPs) are a class of important materials with widespread applications due to their chem-ical stability and high photothermal conversion efficiency.
Electrocatalytic CO2 reduction reaction(CO2RR) converts CO2 into valuable chemical fuels,which can effectively alleviate global warming and energy crisis.However,limited by its slow reaction rate and low product selectivity,it is urgent to design efficien