论文部分内容阅读
自从1978年Goldberg等首次报道了在(+)-R-N-十二烷基-N,N-二甲基-α-苯基乙基铵盐所形成的手性胶束中,还原前手性酮得到醇(e.e.％仅为1.7％)以来,我们通过增加表面活性剂的键长及改变其结构已有效地提高
Since 1978, Goldberg et al. First reported the reduction of prochiral ketones in chiral micelles formed by (+) - RN-dodecyl-N, N-dimethyl-α-phenylethylammonium salts Since getting the alcohol (ee% only 1.7%), we have effectively increased by increasing the bond length and changing the structure of the surfactant