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通过具体的实验数据,对溶液反应与气相反应动力学特征的差异进行了对比。对采用“溶剂笼”、“遭遇对”模型并引入扩散过程对溶液反应进行处理的经典过程进行了分析,指出该处理过程存在理论假设和近似处理不合理、结果综合性差、无法全面反映溶剂影响等问题。
Through the specific experimental data, the difference between the kinetic characteristics of solution reaction and gas phase reaction was compared. The classical process of solution reaction was introduced by using “solvent cage” and “encounter pair” model and the diffusion process was introduced. It was pointed out that the treatment process had theoretical assumptions and approximate treatment unreasonable, the result was poor in comprehensiveness and could not Fully reflect the impact of solvents and other issues.