【摘 要】
：
在水溶液中合成了标题配合物[Co(pyr)2(sal)2]H2O, 化学式为C24H22N2O5Co,并测定了其晶体结构。晶体属单斜晶系,C2/c空间群。a = 14.654(3),b = 12.247(3),c = 14.060(3) u00
【机 构】
：
江西井冈山师范学院化学系,桂林工学院材化系,广西师范大学化学化工系,广西师范大学化学化工系 江西,吉安343009,广西,桂林541004,广西,桂林541004,广西,桂林541004
论文部分内容阅读
在水溶液中合成了标题配合物[Co(pyr)2(sal)2]H2O, 化学式为C24H22N2O5Co,并测定了其晶体结构。晶体属单斜晶系,C2/c空间群。a = 14.654(3),b = 12.247(3),c = 14.060(3) u001f,β = 116.804(4)°,V = 2252.1(8) u001f3, Mr = 477.37, Z = 4, Dc = 1.408 g/cm3,μ = 0.800 mm-1,F(000) = 988, Co(Ⅱ)原子是六配位的八面体结构。
The title complex [Co (pyr) 2 (sal) 2] H2O was synthesized in aqueous solution with the chemical formula of C24H22N2O5Co and its crystal structure was determined. Crystals are monoclinic, C2 / c space group. a = 14.654 3, b = 12.247 3, c = 14.060 3 u001f, β = 116.804 4 °, V = 2252.1 (8) u001f3, Mr = 477.37, Z = 4, Dc = 1.408 g / cm3, μ = 0.800 mm-1 and F (000) = 988. The Co (Ⅱ) atom is a hexacoordinated octahedral structure.
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