Synthesis and Crystal Structure of Novel Sn-O Clusters Generated from ~nBu_2SnO and Esters

• 作 者: 雷斌 贾永光 柳凌艳 常卫星 李靖
• 机 构: StateKeyLaboratoryandInstituteofElemento-organicChemistry
• 出 处: 结构化学
• 发表日期: 2010年9期
• 关键词: 晶体结构 直接合成 锡原子 集群 酯 三斜晶系 单斜晶系 核磁共振 dibutyltin oxide Sn-O cluster X-ray diffractio

A facile and credible strategy was demonstrated to synthesize two new Sn-O clusters 1 and 2 by the reactions of nBu2SnO with esters directly under mild conditions.Cluster 1 crystallizes in the triclinic system,space group P1 with a = 13.054(3),b = 13.137(