【摘 要】
：
On the basis of the proposed structures of jiangrines C and D, a synthetic strategy was initiated from D-glyceraldehyde acetonide,a readily available chiral mat
【机 构】
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Key Laboratory of Green Chemistry & Technology of Ministry of Education,College of Chemistry, Sichua
【出 处】
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Science China(Chemistry)
论文部分内容阅读
On the basis of the proposed structures of jiangrines C and D, a synthetic strategy was initiated from D-glyceraldehyde acetonide,a readily available chiral material. Through a linear seven-step synthesis, the target molecules were accomplished. However, all characteristic data of the synthetic 3 and 4 were found to be different from those of natural jiangrines C and D. Accordingly, the molecular structures of jiangrines should be revised and a possible molecular skeleton for them was proposed.
On the basis of the proposed structures of jiangrines C and D, a synthetic strategy was initiated from D-glyceraldehyde acetonide, a readily available chiral material. However, all characteristic data of the synthetic 3 and 4 were found to be different from those of natural jiangrines C and D., the molecular structures of jiangrines should be revised and a possible molecular skeleton for them was proposed.
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