Three new MOFs with unusual CuII6 cluster, linear CuII chain and triangular CuII3 core motifs tuned

• 作 者: YANG EnCui WANG XiuGuang ZHANG
• 机 构: TianjinKeyLaboratoryofStructureandPerformanceforFunctionalMolecules,CollegeofChemistry
• 出 处: 中国科学：化学英文版
• 发表日期: 2013年4期
• 关键词: 结构导向剂 磺酸基 磁学性质 集群 合成 三角 直链 反铁磁相互作用 4-amino-l 2 4-triazole polynuclear metal clu
• 基金项目: This work was financially supported by the National Natural Science Foundation of China （20703030, 20871092）, the Program for New Centu- ry Excellent Talents in University （NCET-08-0914）, and the Natu

Three new MOFs with the same components but different structures and magnetic behavior, {[Cu6(atr)6(H2O)2(μ3 OH)2(SO4)5 ]·5.25H2O} n (1), {[Cu2(atr)2( -OH)2(SO4 )]·3H2O} n (2), and {[Cu7(atr)6(H2O)6(μ3-OH)2(SO4 )6 ]·2H2O} n (3) (atr = 4-ami