Preparation and Ionic Conductivity of Ultrafine Li_(2+x)RE_xSi_(1-x)O_3 by Sol-Gel Method

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:nini126
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Li 2+ x RE x Si 1- x O 3(RE=Pr, Nd, Sm, Gd; x =0~0 15) samples were prepared by the sol gel method. DTA TG, XRD, TEM and A C impedance techniques were used to investigate the structure, shape, and ionic conductivity of these samples. The results show that the range of solid solution formation is in 0< x ≤0 09, in which the conductivity of these samples raises with the increasing amount of RE 2O 3 (RE=Pr, Nd, Sm, Gd) added, and the diameter of the powders is about 100 nm. Compared with the conventional solid state reaction, the sol gel method needs low temperature and presents high ionic conductivity. Li 2+ x RE x Si 1- x O 3 (RE = Pr, Nd, Sm, Gd; x = 0-015) samples were prepared by the sol gel method. DTA TG, XRD, TEM and AC impedance techniques were used to investigate the structure, shape, and ionic conductivity of these samples. The results show that the range of solid solution formation is in 0
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