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  5. The cage effect on assembly of cyclic-bis-(zinc porphyrin) with 5,15-dipyridylporphyrin

The cage effect on assembly of cyclic-bis-(zinc porphyrin) with 5,15-dipyridylporphyrin

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：ahcyw
【摘 要】
：
An inclusion complex of cyclic bis(zinc porphyrin) 1 with 5,15-dipyridylporphyrin derivative 3 has been designed and constructed. The complex formation is induc
【作 者】
：
ZaiChun Zhou (1) (2)  YiZhou 
【机 构】
：
1.StateKeyLaboratoryandInstituteofElemento-organicChemistry,2.CollegeofChemicalandEngineering
【出 处】
：
中国科学：化学英文版
【发表日期】
：
2009年9期
【关键词】
：
CAGE effect CYCLIC bis(zinc porphyrin) ASSEMBLY template-directed synthesis cage 
【基金项目】
：
Supported by the 973 Program (Grant No. 2006CB932900),National Natural Science Foundation of China (Grant Nos. 20802038 and 20721062),Tianjin Natural Science Foundation (Grant No. 07QTPTJC29700).
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An inclusion complex of cyclic bis(zinc porphyrin) 1 with 5,15-dipyridylporphyrin derivative 3 has been designed and constructed. The complex formation is induced by Zn-N coordination, and is robust (Kassoc ~ 106 L/mol) due to the presence of the cage eff
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