酶促酮酸酯还原合成(S)-2-乙酰氧基十三烷

• 作 者: 陈胜洲 李焰 陈祖兴
• 机 构: 湖北大学化学与材料科学学院,湖北大学化学与材料科学学院,湖北大学化学与材料科学学院 武汉430062,武汉430062,武汉430062
• 出 处: 应用化学
• 发表日期: 2002年01期
• 关键词: (S)-乙酰氧基十三烷 酶促还原反应 合成 信息素

S)-2-Acetoxyltridecane, which is the aggregation pheromone of Drosophila Mulleric and the sex pheromone component of the pea midge (Contarinia pisi), was synthesized from ethyl acetoacetate by enzymatic reduction with bakers yeast in the presence of ethyl chloroacetate as a key step. The optical purity of the target product is about 98%e.e.

S) -2-Acetoxyltridecane, which is the aggregation pheromone of Drosophila Mulleric and the sex pheromone component of the pea midge (Contarinia pisi), was synthesized from ethyl acetoacetate by enzymatic reduction with baker s yeast in the presence of ethyl chloroacetate as a key step. The optical purity of the target product is about 98% ee