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本文报道B_(12)H_(12)~(2-)、B_(10)H_(10)~(2-)、B_9H_9~(2-)、B_(11)H_(14)~-及B_3H_8~-阴离子化合物分别与C_5H_5FeC_5H_4CH_2N(H)Me_2Cl[Ⅲ]和Fe(C_5H_4CH_2N(H)Me_2Cl)_2[Ⅳ]反应合成了它们的衍生物并研究了它们的反应性能。发现C_3H_6FeC_5H_4CH_2N(H)Me_2B_3H_8不稳定,在不同的条件下降生成C_5H_5FeC_5H_4CH_2NMe_2·BH_3[X],B_9H_9~(2-)及B_(11)H_(14)~-与[Ⅲ]反应时硼化物发生降解也得到化合物[Ⅹ]。并测定了[C_5H_5FeC_5H_4CH_2N(H)Me_2]_2B_(12)H_(12)的晶体结构。
In this paper, the effects of B_ (12) H_ (12) ~ (2), B_ (10) H_ (10) ~ 2, B_9H_9 ~ (2), B_ (11) H_ (14) ~ and B_3H_8 ~ - Anionic compounds were synthesized with C_5H_5FeC_5H_4CH_2N (H) Me_2Cl [Ⅲ] and Fe (C_5H_4CH_2N (H) Me_2Cl) _2 [Ⅳ] respectively. Their derivatives were synthesized and their reactivity was studied. It was found that C_3H_6FeC_5H_4CH_2N (H) Me_2B_3H_8 was unstable and the formation of C_5H_5FeC_5H_4CH_2NMe_2 · BH_3 [X], B_9H_9 ~ (2-) and B_ (11) H_ (14) ~ - Compound [X] is obtained. The crystal structure of [C_5H_5FeC_5H_4CH_2N (H) Me_2] _2B_ (12) H_ (12) was also determined.