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The reaction of 1,2-benzenedicarboxylic acid(H2L) with Zn(NO)3·6H2O and selfdesigned 1,2-bis(imidazol-1-ylmethyl)-benzene)(2-bimb) in DMA/H2 O results in the forming of double chains ZnⅡ complex, {[Zn2.5(L)2(bimb)(H2O)]·H2O}n(1), which has been