A Novel Polymethyl Methacrylate (PMMA)-TiO_2 Nanocomposite and Its Thermal and Photic Stability

来源 :Wuhan University Journal of Natural Sciences | 被引量 : 0次 | 上传用户:zongduzhicai
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A new kind of polymethyl methacrylate (PMMA)-TiO_2 nanocomposite was synthesized through polymerization. The thermal and photic stability of this PMMA-TiO_2 nanocomposites were investigated. The as-prepared samples were characterized by scanning electron microscopy (SEM), UV-Vis spectroscopy, differential thermal analysis (DTA) and the photo-induced weight loss. The results show that the photostability of the PMMA-TiO_2 nanocomposite is higher than that of the pure PMMA under UV-light irradiation. The weight-loss of the pure PMMA reaches 30% after 300 h UV-irradiation, while the composite only 0.3% under the identical experimental condition. The glass transition temperature (T_g) of pure PMMA is only 80 ℃, while the T_g of the composite reaches 258 ℃. Compared with pure PMMA, the thermal stability of the composite is greatly enhanced. The thermal-and photic stability of this PMMA-TiO 2 nanocomposites were investigated. The as-prepared samples were characterized by scanning electron microscopy (SEM), UV-Vis spectroscopy The results show that the photostability of the PMMA-TiO 2 nanocomposite is higher than that of the pure PMMA under UV-light irradiation. The weight-loss of the pure PMMA reaches 30% after 300 h UV-irradiation, while the composite only 0.3% under the identical experimental condition. The glass transition temperature (T_g) of pure PMMA is only 80 ° C. while the T_g of the composite reaches 258 ° C. Compared with pure PMMA , the thermal stability of the composite is greatly enhanced.
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