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The phase diagram of system NdCl<sub>3</sub>-LiCl-KCl has been investigated by DTA.Six surfacescorresponding to the prhnary crystallization of NdCl<sub>3</sub>,LiCl,KCl,γ-KCl·NdCl<sub>3</sub>,β-3KCl·NdCl<su