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本文简述了乳浓聚合动力学研究的进展,着重于澳大利亚Sydney大学Gilbert等在乳液聚合阶段Ⅱ动力学方面的研究概况。介绍了不同水溶性单体的小尺寸种子乳液体系的SmithEwart递推方程的求解方法及其解析解形式和乳液聚合动力学数据的处理。同时讨论了该研究的局限性。
In this paper, the progress of kinematic studies of emulsion polymerization was briefly reviewed, focusing on the research overview of Gilbert et al. At Sydney University in Australia in the kinetics of emulsion polymerization. The solving method of SmithEwart recursion equation of small size seed emulsion system with different water-soluble monomers and its analytical solution and the data processing of emulsion polymerization kinetics are introduced. The limitations of the study are also discussed.