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采用机械合金化法制备了两相颗粒极细的Cu-20Cr与Cu-40Cr合金,研究其在700~800℃,0.1MPa纯氧气中的氧化.MACu-20Cr及MACu-40Cr合金24h氧化后均形成了连续的Cr2O3层,这主要由于两相颗粒的细化,加快了Cr颗粒的溶解,缩短了Cr的扩散距离,从而有效地促进Cr2O3层的形成.
The Cu-20Cr and Cu-40Cr alloys with very fine two-phase particles were prepared by mechanical alloying and the oxidation of pure Cu-20Cr and Cu-40Cr was studied at 700-800 ℃ and 0.1MPa pure oxygen. After continuous oxidation of MACu-20Cr and MACu-40Cr alloys, the continuous Cr2O3 layer was formed after 24h oxidation. This was mainly due to the refinement of the two-phase particles, which accelerated the dissolution of Cr particles and shortened the diffusion distance of Cr, thereby effectively promoting the Cr2O3 layer form.