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A new bismuth compound Bi(Hsal)3(1,10-phenanthroline) (Hsal=O2CC6H4-2-OH) has been synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in the triclinic system, space group P1, with a=10.243(2), b=11.905(3), c=12.934(3), α=76.780(6), β=68.683(6), γ=80.930(7)o, V=1425.6(5)3, Dc=1.865 g/cm3, Mr=800.51, F(000)=780, μ= 6.247 mm-1, Z=2, R=0.0456 and wR=0.1131 for 5612 observed reflections (I > 2σ(I)). In this compound, three salicylate ligands coordinate to the Bi atom through the carboxylate groups to form a four-membered chelate ring, and phenanthroline ligand chelates the metal through two N atoms. The structure of the title compound manifests a possible coordination mode between bismuth subsalicylate and N atom containing amino acid in the biological system.
A new bismuth compound Bi (Hsal) 3 (1,10-phenanthroline) (Hsal = O2CC6H4-2-OH) has been synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in the triclinic system, space group P1, with a = 10.243 (2), b = 11.905 (3), c = 12.934 (3) , α = 76.780 (6), β = 68.683 (6), γ = 80.930 ) 3, Dc = 1.865 g / cm3, Mr = 800.51, F (000) = 780, μ = 6.247 mm- 1, Z = 2, R = 0.0456 and wR = 0.1131 for 5612 observed reflections )). This compound, three salicylate ligands coordinate to the Bi atom through the carboxylate groups to form a four-membered chelate ring, and phenanthroline ligand chelates the metal through two N atoms. The structure of the title compound manifests a possible coordination mode between bismuth subsalicylate and N atom containing amino acid in the biological system.