Synthesis and Crystal Structure of a New Mononuclear Cobalt（Ⅲ） Complex with 2,2＇-Dipyridylamine and

• 作 者: CHEN Jun XU Xing-You GAO Jian
• 机 构: DepartmentofChemtcalEngmeering,CoordinationChemistryInstitution,MaterialsChemistryLaboratory
• 出 处: 结构化学
• 发表日期: 2007年2期
• 关键词: 钴 晶体结构 合成工艺 氨基酸 cobalt complex mononuclear crystal structure
• 基金项目: This project was supported by the Natural Science Foundation of Jiangsu Province （BK2005045）, the Key Marine Biotechnology Lab. of HHIT and the Natural Science Foundation of HHIT （Z.2005016）

A new mononuclear cobalt(III) complex [Co(dpa)2(Gly)](ClO4)2′4H2O was synthesized by the reaction of Co2+, glycine (gly) and 2,2′-dipyridylamine (dpa) in a methanol-water solution, and its structure was characterized by IR, EA, ES-MS and X-ray structure a