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气固相催化反应中的振荡,自1968年首先在CuO催化剂上N_2O的分解反应中被实验观察以后,已日益受到人们的关注。它是当前化学反应工程中受人重视的一个新课题。本文是关于这一课题近年发展情况的文献综述,共包括了至1983年止的45篇文献,内容主要介绍:多相催化反应振荡现象研究的理论意义和实用价值;它的研究现状,已取得的主要实验结果和有关的理论解释;多相催化反应振荡的数学模型;强制振荡—反应器的周期操作;当前对于这一课题的研究趋势。
Oscillation in the gas-solid phase catalytic reaction has been gaining more and more attention since it was firstly experimentally observed in the decomposition of N 2 O on a CuO catalyst in 1968. It is a new subject that people attach importance to in the current chemical reaction engineering. This article is a literature review on the development of this subject in recent years, including a total of 45 articles until 1983, the main content: the theoretical significance and practical value of the study of the phenomenon of heterogeneous catalytic reaction oscillation; its research status has been made The main experimental results and related theoretical explanations; Mathematical model of heterogeneous catalysis oscillation; Forced oscillation - Periodic operation of the reactor; Current research trends on this topic.